Targeted synthesis of electroactive porous organic frameworks containing triphenyl phosphine moieties-Reference-Cited by-同舟云学术

Targeted synthesis of electroactive porous organic frameworks containing triphenyl phosphine moieties

Published:2013-10-13 Issue:2000 Volume:371 Page:20120312
ISSN:1364-503X
Container-title:Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences
language:en
Short-container-title:Phil. Trans. R. Soc. A.

Author:

Pei Cuiying¹,Ben Teng²,Guo Han¹,Xu Jun³,Deng Feng³,Xiang Zhonghua⁴,Cao Dapeng⁴,Qiu Shilun¹

Affiliation:

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, People’s Republic of China

2. Department of Chemistry, Jilin University, Changchun, People’s Republic of China

3. State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Wuhan, People’s Republic of China

4. Division of Molecular and Materials Simulation, Key Laboratory for Nanomaterials, Ministry of Education of China, Beijing University of Chemical Technology, Beijing, People’s Republic of China

Abstract

A novel electroactive porous aromatic framework (JUC-Z4-Cl) was designed and synthesized via Yamamoto-type Ullmann cross-coupling reaction with the monomer tris(4-chlorophenyl)phosphine. By simple redox chemical reactions, stable, reductive, porous polytri( p -phenyl)phosphine (JUC-Z4) and polytri( p -phenyl)phosphine oxide (JUC-Z5) could be obtained as off-white powders. The structures of JUC-Z4 and JUC-Z5 were confirmed using magic-angle spinning nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, etc. The microporous architectures exhibit high stability (471°C for JUC-Z4 and 484°C for JUC-Z5) and large surface area (793 and 648 m 2 g −1 for JUC-Z4 and JUC-Z5, respectively). JUC-Z4 also exhibits efficient recognition ability of greenhouse gases from dry air.

Publisher

The Royal Society

Subject

General Physics and Astronomy,General Engineering,General Mathematics

Link

https://royalsocietypublishing.org/doi/pdf/10.1098/rsta.2012.0312

Reference36 articles.

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