Abstract
A detailed study of the kinetics of the raction H + NO +
M
= HNO +
M
+ 49.9 kcal/mole (1) shows that all the third bodies examined except H
2
O give similar relative efficiencies for the formation of ground state (
1
A
') and electronically excited (
1
A
") HNO. The overall rate constants found at 293°K (in cm
6
mole
-2
s
-1
x 10
-16
) are: Ar, 1.11 ± 0.15; H
2
, 2.07 ± 0.18; CO
2
, 2.26 ± 0.23; N
2
O, 2⋅45 ± 0⋅44; SF
6
, 3.96 ± 0.46; H
2
O, 6.8 ± 1.2. For the reaction D + NO + Ar = DNO + Ar a rate constant of (1.28 ± 0.21) x 10
16
cm
6
mole
-2
s
-1
was obtained. The relative third body efficiencies in reaction (1) were less similar to the closely related Process H + O
2
+
M
= HO
2
+
M
+ 47.1 kcal/mole than to the reaction O + NO +
M
= NO
2
+
M
+ 73.2 kcal/mole.
Reference35 articles.
1. a b c d 6
2. M = H 2 5-5 He +80/ Ar 100 c o 2 8-5 n 20 ---------- s f 6 14-7 h 20 350» 1-87 ---------- ---------- 1-82
3. [0-87]A 0-83 1-36 0-47 1-00 1-00 1-00 1-00 2-05 2 1 6 3-84 3-72 2-21 2 1 6 ---------- ----------
4. 3-58 2-67 ---------- ----------
5. 6-15 6-34 ---------- 13-7
Cited by
73 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献