An expansion method for calculating atomic properties. IX. The dipole polarizabilities of the lithium sequence*

Author:

Abstract

A theory is developed for expanding the dipole polarizabilities and shielding factors of an atom or ion in inverse powers of the nuclear charge Z in cases where the field links degenerate zero order configurations. Results for all members of the lithium isoelectronic sequence are presented both within the Hartree-Fock approximation and in a more accurate formulation, and are found to be in agreement with earlier work.

Publisher

The Royal Society

Subject

Pharmacology (medical)

Reference15 articles.

1. Bethe H. A. & Salpeter E. E. 1957 Quantum mechanics of one and two electron atoms. Berlin: Springer-Verlag.

2. Chisholm C. D. H. & Dalgarno A. 1965 Proc. Roy.

3. First-order Solutions of Atomic Hartree-Fock Equations

4. Proc. Roy;Cohen M.;Soc. A,1963

5. Proc. Roy;Cohen M.;Soc. A,1962

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1. Quadrupole and octupole polarizabilities for the ground states of lithiumlike systems from Z=3 to 20;The Journal of Chemical Physics;2004-09

2. Dipole polarizabilities for the ground states of lithium-like systems from Z=3 to 50;Journal of Physics B: Atomic, Molecular and Optical Physics;1994-03-14

3. Z-Expansion Methods;Advances in Atomic and Molecular Physics;1989

4. Multipole polarizabilities for hydrogenic bound states;Physical Review A;1984-03-01

5. Dipole Polarizability, Radius and Ionization Potential for Atomic Systems;Physica Scripta;1983-06-01

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