Abstract
Pulse radiolysis of solutions of iodine in
cyclo
hexane resulted in the formation of a transient absorption with wavelength maximum at 3300 Å. This transient spectrum was assigned to the C
6
H
12
... I' charge-transfer complex. The spectrum and extinction coefficients of the complex over the wavelength range 2500 to 6500 Å were obtained, the coefficient at 3300 Å being 2025 1. mole
-1
cm
-1
. Hydrogen iodide in
cyclo
hexane gave rise to the same transient absorption. Pulse radiolysis of
cyclo
hexane and
cyclo
hexyl iodide alone gave rise to different transient spectra attributed to the
cyclo
hexyl radical, absorbing in the ultraviolet, extinction coefficient 3401. mole
-1
cm
-1
at 2550 Å and the C
6
H
11
.. .I* charge-transfer complex, absorption maximum 3900 A, extinction coefficient ~ 10
3
to 10
4
1. mole
-1
cm
-1
, respectively. During the course of the investigations rate constants were obtained for the following reactions: C
6
H
11
+ I
2
C
6
H
11
I + I',
k
II
= 7 x 10
9
1. mole
-1
s
-1
, 2C
6
H
12
...I' -> 2C
6
H
12
+ I
2
,
k
II
= 1.06 x 10
10
1. mole
-1
s
-1
, or 21' -> I
2
,
a
C
6
H
10
+ C
6
H
12
2C
6
H
11
k
11a
+
k
11b
=2.5 x 10
9
1. mole
-1
s
-1
bC
12
H
22
Dilute solutions of iodine (10
-4
M) in
cyclo
hexane yielded experimental evidence for neutral radical intermediates only. There were, however, indications that ionic radical intermediates occur in more concentrated solutions ( > 10
-3
M). :
Reference21 articles.
1. Pulse Radiolysis
2. Bertin E. P. & Hamill W. H. 1964
3. Bridge N. K. i 960 J. Chem. Phys. 32 945. J.Amer. Chem. Soc. 86 1301.
4. Absorption Spectra ofF2−,Cl2−,Br2−, andI2−in the Alkali Halides
5. Proc. Roy;Edgecombe F. H. C.;Soc. A,1959
Cited by
41 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献