Abstract
The gaseous oxidation of acetone has been studied at temperatures between 250 and 510°C at pressures up to 450 mmHg. In contrast to earlier reports, two oxidation régimes have been discovered, separated by a region where the rate of reaction decreases as the temperature rises. This paper presents the results of a detailed study of the kinetics and products of the reaction in the high-temperature region. The reaction is autocatalytic, and a reaction scheme is proposed which accounts for the principal experimental facts. This scheme involves degenerate chain branching, in which the oxidation of formaldehyde plays an important part.
Reference41 articles.
1. Avramenko Y. A. & Neimann M. B. 1939 Acta Physico-chim. 10 601.
2. Proc. Boy;Bardwell J.;Soc. A,1951
3. Proc. Boy;Bardwell J.;Soc. A,1950
4. Proc. Boy;Bardwell J .;Soc. A,1951
5. THE OXIDATION OF FREE ALKYL GROUPS. PHOTO-OXIDATION OF GASEOUS METHYL IODIDE
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