High-resolution nuclear-magnetic-resonance spectra of hydrocarbon groupings - V. ABCX spectra of vinyl fluoride and 3-methylbut-l-ene-Reference-Cited by-同舟云学术

High-resolution nuclear-magnetic-resonance spectra of hydrocarbon groupings - V. ABCX spectra of vinyl fluoride and 3-methylbut-l-ene

Published:1961-08-22 Issue:1312 Volume:263 Page:136-148
ISSN:0080-4630
Container-title:Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
language:en
Short-container-title:Proc. R. Soc. Lond. A

Author:

Abstract

Some general properties of ABCX -type spectra are discussed. It is shown that it is possible to deduce from such spectra the relative signs of all inter-nuclear coupling constants. Analyses are presented of the hydrogen (proton) spectra from the vinyl groups of vinyl fluoride and 3-methylbut-l-ene, and of the fluorine spectrum of the former molecule. It is shown that all HF coupling constants in vinyl fluoride are of the same sign as the cis and trans HH coupling constants.

Publisher

The Royal Society

Subject

Pharmacology (medical)

Link

https://royalsocietypublishing.org/doi/pdf/10.1098/rspa.1961.0152

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