II. The lattice resonances of ionic crystals

Author:

Abstract

Sixteen crystalline ionic halides have been studied in transmission and reflexion experiments in the range 70 to 250 μ at temperatures down to 4 °K. The lattice resonances have been clearly observed, their characteristic frequencies accurately determined and the degree of damping investigated as a function of temperature. The significance of the results is discussed from the point of view of various models of dielectric behaviour—in particular the refinements of the Born-Lorentz model which cover the effect of distortion moments due to the overlap of neighbouring ions. Discrepancies remain between theory and experiment which have a bearing on the calculation of vibration spectra.

Publisher

The Royal Society

Subject

Pharmacology (medical)

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