A mass spectrometer for studying chemical reactions

Author:

Abstract

This paper describes a mass spectrometer designed to study gas-phase chemical kinetics. An ion source has been constructed which incorporates a differentially pumped, electron beam filament chamber, and line-of-sight access from the sampling pinhole to the ionization region. Experiments are described which test the effectiveness of differential pumping in reducing contamination of the sample by pyrolysis products formed from the sample on the hot filament.

Publisher

The Royal Society

Subject

Pharmacology (medical)

Reference8 articles.

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1. Mass spectrometric sampling of ions from atmospheric pressure flames—III: Boundary layer and other cooling of the sample;Combustion and Flame;1977-01

2. The occurrence of chemical reactions in supersonic expansions of a gas into a vacuum and its relation to mass spectrometric sampling;Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences;1971-05-04

3. Mass spectrometric study of the photolysis of CH3I+NO mixtures;Transactions of the Faraday Society;1970

4. Mass spectrometric study of the reaction of nitrogen atoms with acetaldehyde;Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences;1968-01-02

5. The qualitative detection of free radicals using a modified commercial mass spectrometer;Journal of Scientific Instruments;1966-09

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