Abstract
A systematic investigation of the temperature variation of the effective Grüneisen parameter, γ
eff.
, has been carried out for the caesium chloride structure, on a model incorporating the Coulomb potential between the ions and a nearest neighbour interaction varying as
r
-n
. As the value of
n
is increased from 8 to 30, the low temperature limit γ
0
of γ
eff.
is progressively reduced, while the high temperature limit γ
∞
increases. The value of γ
0
— γ
∞
is positive for
n
≤ 15 and changes sign for
n
≥ 20. Thus the trend and the extent of the temperature variation of γ
eff.
are sensitive to the value of
n
in the caesium chloride lattice. On the other hand in the NaCl lattice, the trend of the temperature variation of γ
eff.
is not affected by a variation of
n
. For
n
≈ 16, the γ
eff.
value appears to be independent of temperature, though the individual Grüneisen parameters for the lattice frequencies vary widely. This case is an example of a type of perfect Grüneisen solid, the condition for the existence of which was given by Blackman. The Houston method with a constant normalization factor is shown to yield the correct trend of the temperature variation of γ
eff.
. A more elaborate normalization procedure alters the γ
eff.
values only slightly. Varying the ratio of the ionic masses has only a slight effect on γ(
p
) and γ
eff.
. From the recently measured elastic data, it appears probable that the value of
n
pertinent to the caesium halides is about 15.
n
may increase slightly with increasing size of the anion. If this value of
n
is correct, the effective Gruneisen parameters for the caesium halides must vary only slightly with temperature. Probably one of the caesium halides will exhibit closely the behaviour of a perfect Grüneisen solid.
Reference16 articles.
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