Abstract
Theoretical and experimental work has been carried out on the quadrupole interaction constant,
B
, for the ground state of manganese, whose ground configuration is a half-filled
d
shell. In the non-relativistic limit B = 0. The theory is based on a new relativistic calculation involving the use of an effective operator acting between non-relativistic states, and a non-vanishing value of
B
has been obtained. To check the theory, the hyperfine structure of the ground state of manganese has been remeasured by the method of atomic beams and an experimental value of
B
has been found. The results are
B
rei
. ≈ — 0.019 Mc/s,
B
expt> = — 0.0183 ± 0.0008 Mc/s. The agreement is satisfactory as to sign and order of magnitude, but high precision is not claimed for the theoretical result
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