Iron coordination in liquid FeAl <sub>2</sub> O <sub>4</sub>-Reference-Cited by-同舟云学术

Iron coordination in liquid FeAl ₂ O ₄

Published:2023-08-28 Issue:2258 Volume:381 Page:
ISSN:1364-503X
Container-title:Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences
language:en
Short-container-title:Phil. Trans. R. Soc. A.

Author:

Drewitt James W. E.¹²^ORCID,Barnes Adrian C.¹^ORCID,Jahn Sandro³^ORCID,Brooker Richard A.²^ORCID,Hennet Louis⁴⁵^ORCID,Neuville Daniel R.⁶^ORCID,Fischer Henry E.⁷^ORCID

Affiliation:

1. School of Physics, University of Bristol, H H Wills Physics Laboratory, Tyndall Avenue, Bristol BS8 1TL, UK

2. School of Earth Sciences, University of Bristol, Wills Memorial Building, Queens Road, Bristol BS8 1RJ, UK

3. Institute of Geology and Mineralogy, University of Cologne, Zuelpicher Strasse 49b, Cologne 50674, Germany

4. Interfaces, Confinement, Matériaux et Nanostructures (ICMN), CNRS, Université d’Orléans, Orléans Cedex 2 45071, France

5. Conditions Extrêmes et Matériaux: Haute Température et Irradiation (CEMHTI), CNRS, Université d’Orléans,Orléans Cedex 2 45071, France

6. Géomatériaux, Institut de Physique du Globe de Paris (IPGP), CNRS, Institut de physique du globe de Paris, Université de Paris Cité,1 rue Jussieu, Paris 75005, France

7. Institut Laue-Langevin, 71 Avenue des Martyrs, CS 20156,Grenoble Cedex 9 38042, France

Abstract

The structure of aerodynamically levitated liquid FeAl 2 O 4 was measured by neutron diffraction with isotope substitution (NDIS). Classical and ab initio molecular dynamics simulations were performed and their results were found to be in close agreement with each other and the NDIS data. The results reveal that molten FeAl 2 O 4 may be considered as an ionic liquid without any preference for particular short-range structural motifs. This article is part of the theme issue ‘Exploring the length scales, timescales and chemistry of challenging materials (Part 1)’.

Funder

Engineering and Physical Sciences Research Council

Publisher

The Royal Society

Subject

General Physics and Astronomy,General Engineering,General Mathematics

Link

https://royalsocietypublishing.org/doi/pdf/10.1098/rsta.2022.0351

Reference46 articles.

1. The effect of oxidation state on the viscosity of melts in the system Na2O-FeO-Fe2O3-SiO2

2. Fe in magma—an overview;Wilke M;Ann. Geophys.,2005

3. Effect of oxygen fugacity on the glass transition, viscosity and structure of silica- and iron-rich magmatic melts

4. X-ray Absorption Near-Edge Structure (XANES) Spectroscopy

5. Mysen B Richet P. 2019 Chapter 11—Structure of iron silicate glasses and melts. In Silicate glasses and melts (eds B Mysen P Richet) pp. 403–430 2nd edn. Amsterdam the Netherlands: Elsevier.

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