Abstract
Films of poly-
γ
-methyl-L-glutamate have been prepared with a high degree of orientation. X-ray photographs show that the least dimensions of the unit cell are
a
= 11·95 Å,
b
= 20·70 Å,
c
= 43·2 Å (fibre axis). One near-meridional reflexion, if produced by the same crystalline phase, requires doubling of the length of the
c
-axis. If all the observed reflexions arise from a single phase, no structure hitherto proposed for the
α
-fold will completely explain the intensities. However, the general pattern of intensities of non-meridional reflexions is in at least qualitative agreement with that calculated by Cochran & Crick for the
α
-helix. The significance of the infra-red dichroism of polypeptides is discussed, and compared with the dichroism observed in the C ═O stretching band in acetanilide. Measurements of the density of poly-
γ
-methyl-L-glutamate are reported, and compared with the value calculated on the
α
-helix model.
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