A high-performance Ni-CeO 2 /Ni/Ni-Y 2 O 3 ·ZrO 2 three-layer anode for direct iso-octane feeding of solid oxide fuel cells

Abstract

Solid oxide fuel cells (SOFCs) directly fed with iso-octane are expected to be power sources for mobile devices and automobiles. However, the conventional anode catalysts nickel (Ni) or cerium oxide (CeO 2 ) used for direct feeding of iso-octane do not suppress carbon deposition or generate high power. In this study, we investigated the Ni-CeO 2 /Ni/Ni-yttria-stabilized-zirconia (YSZ) three-layer anode to establish the suppression of carbon deposition and high-power generation in the SOFC. The anode consists of a Ni-CeO 2 catalyst layer as the top layer, an Ni catalyst layer as the second layer, and a Ni-YSZ catalyst layer as the third layer on top of the electrolyte. The concept of the three-layer anode is as follows: fuel reforming occurs in the Ni-CeO 2 layer, the reformed H 2 or CO is electrochemically oxidized in the Ni-YSZ catalyst layer, and the Ni catalyst middle layer prevents the reaction between YSZ and CeO 2 . Scanning electron microscopy and electrochemical characterization confirmed carbon deposition suppression and improved power generation. The anode showed no carbon deposition and generated high-power, 600 mA cm −2 and 150 mW cm −2 , at 950°C and a steam/carbon ratio of 3.0. Additionally, we discuss the fuel reforming reactions on the three-layer electrode by the results of exhaust gas analysis.