Enhancement of flaky graphite cleaning by ultrasonic treatment

Abstract

In this study, the aim is to simplify the graphite cleaning process. In order to achieve flotation for graphite effectively, ultrasonic treatment was used as a pre-treatment technique. Flotation tests were conducted using different ultrasound power and ultrasonic treatment time. The influences of ultrasonic treatment on particle sizes, morphologies, wettability, the content of surface elements and on the flotation effect of flaky graphite were investigated. The results of ultrasonic treatment for graphite flotation were compared with the results of conventional flotation. The results showed that ultrasonic treatment not only changed the size of flaky graphite, but also eliminated impurities on the graphite surface. Additionally, the ultrasonic treatment improved the hydrophobicity of graphite. It was observed that ultrasound can remove not only silicate impurities but also most other metal impurities. The yield, carbon content and recovery of flotation concentrate were 91.46%, 95.17% and 96.12% after ultrasonic treatment for 4 min with ultrasound power 1600 W, which were 5.83%, 2.86% and 8.84% higher than that of conventional flotation, respectively. The graphite after ultrasonic treatment was conducted only one times flotation, the carbon content in concentrate products had reached 95%. This study indicates that intensifying graphite flotation by ultrasonic treatment can shorten the graphite cleaning process.