Abstract
A general theory is outlined for the transport of charge and the convective dispersion of charged species through a spatially periodic porous medium under the influence of a homogeneous, Darcy-scale electric field
Ē
, as well as a homogeneous applied pressure-gradient field
∇
¯
p
¯
. The particulate surfaces of the porous medium are characterized as possessing a non-uniform surface charge, with thin, Helmholtz double layers bordering the charged surfaces in the interstitial fluid phase. The theory uses a straightforward application of macrotransport theory, as well as standard methods of analysis of transport phenomena in spatially periodic systems, to derive, first, general expressions for the following four Darcy-scale, electromechanical-transduction property dyadics: (i) the effective electrical conductivity
σ
¯
; (ii) the hydraulic permeability
K
¯
; (iii) the ‘streaming potential’ coupling dyadic
K
¯
P
C
; and (iv) the ‘electroosmotic’ coupling dyadic
K
¯
E
C
. General formulas for these gross-scale, phenomenological coefficients are provided in terms of four spatially periodic, microscale dyadic fields (
∇
g
,
∇
h
,
V
,
V
E
). Unit-cell, boundary-value problems are derived for determining these latter dyadics as functions of the microscale geometrical and physicochemical nature of the porous material. In addition, formulas for computing the mean velocity
U
¯
∗
and dispersivity
D
¯
∗
of a charged, convecting and diffusing Brownian particle (or cluster of particles) are presented. Two explicit examples are offerred to illustrate the implementation of the theory. In the first example, a charged, pointsize, Brownian particle is imagined as convecting and diffusing within a porous medium composed of parallel, charged, rectilinear plates between which a Newtonian fluid flows and an electric field is applied. In the second example, leading-order expressions are derived for the electrokinetic transductive properties (
U
¯
∗
) of a highly porous two-dimensional array of charged circular cylinders though which a Newtonian fluid flows. These leading-order results are found to be in agreement with results appearing in the literature.
Subject
Pharmacology (medical),Complementary and alternative medicine,Pharmaceutical Science
Cited by
20 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献