Abstract
Rate coefficients
k
c
(
j
,
m
) for hitting collisions between ions of charge
e
and linear molecules of quadrupole moment
q
are calculated by the semi-classical adiabatic invariance method. The main results are presented in the form of two graphs of
k̄
c
/
k
L
against √
S
, where
k̄
c
is the thermal average of the rate coefficients
k
c
(
j
,
m
),
k
L
is the Langevin rate coefficient and
S
is a certain dimensionless parameter. The values of
k̄
c
for
eq
negative are greater than those for
eq
positive. A comparison is made with the measured rate coefficients of some proton and deuteron transfer reactions.
Reference23 articles.
1. Ion-polar molecule collisions. A modification of the average dipole orientation theory: The cos θ model
2. Bates D. R. 1982 Proc.
3. J. chem;Celli F.;Phys.,1980
4. Prog;Chesnavich W. J.;Reaction Kinetics,1982
Cited by
52 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献