Abstract
The
v
3
band of NF
2
(X̃
2
B
1
) has been measured at high resolution by using tunable diode lasers. Rotational, distortion and spin-rotation constants have been derived for the
v
3
= 1 state by using ground state constants derived earlier from analysis of the
v
1
band. The position of the band centre, not previously measured, is 942.481 53(30) cm
-1
. Analysis of the
v
1
—
v
3
Coriolis interaction yields the Coriolis coupling constant ξ
13
= 0.698(10).
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