The detection of free radicals in the high intensity photolysis of hydrogen azide-Reference-Cited by-同舟云学术

The detection of free radicals in the high intensity photolysis of hydrogen azide

Published:1956-04-10 Issue:1200 Volume:235 Page:143-147
ISSN:0080-4630
Container-title:Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
language:en
Short-container-title:Proc. R. Soc. Lond. A

Author:

Abstract

The absorption spectra of the radicals NH and NH 2 have been observed in the flash photolysis of hydrogen azide in the presence of an excess of inert gas. A new complex, but slightly diffuse, absorption has been detected around 2700 Å. This spectrum shows no shift when DN 3 is substituted for HN 3 , and it is attributed to the N 3 radical. The mechanism of the hydrogen azide photolysis is discussed briefly with reference to these observations.

Publisher

The Royal Society

Subject

Pharmacology (medical)

Link

https://royalsocietypublishing.org/doi/pdf/10.1098/rspa.1956.0071

Reference20 articles.

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