Lamb shift of a tightly bound electron I. Method

Abstract

A method for calculating the Lamb shift of an inner electron in a heavy atom is developed. This method contains only an expansion in a, the coupling of the electron with the radiation field, but not in Zx , where Z is the atomic number. Since the calculation is essentially non-covariant, care must be taken in eliminating divergent terms. A ‘correct’ finite part of the Lamb shift is obtained, and put into a form suitable for calculation. That this form is convenient will be demonstrated in the following paper where the Lamb shift of a K -electron in Hg is calculated.