Abstract
The reaction between propylene and oxygen has been examined between the temperatures of 340 and 400°C in a static system by detailed analysis supplemented by pressure-time data. The reaction is of the degenerately branched-chain type, and acetaldehyde is mainly responsible for branching. The aldehyde is probably produced by the decomposition of a peroxide which is the initially formed molecular product. Inhibition of certain of the elementary processes which occurs at high concentrations of hydrocarbon is ascribed to the formation of an unreactive allyl radical. Reaction processes which account for the main features of the reaction and the more important intermediates and products are discussed.
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