Abstract
Measurements of the partial charge transfer cross-sections for doubly charged ions
X
2+
+
Y
→
Y
+
+
X
+
are described for C
2+
, N
2+
, A
2+
in He, Ne, A, and the results are discussed in terms of divergence from near-àdiabatic conditions caused by the crossing of potential energy curves. The single endothermic case C
2+
in He behaves adiabatically; all the others, which are exothermic, show large cross-sections at low energies. In the case A
2+
in A there is a contribution from double charge transfer, which cannot be distinguished experimentally from partial charge transfer.
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5. Collisions between atoms and molecules at ordinary temperatures
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