The thermal decomposition of ammonium perchlorate II. The kinetics of the decomposition, the effect of particle size, and discussion of results

Author:

Abstract

Fröhlich has shown that a one-dimensional metal, at absolute zero, can exhibit certain of the properties of a superconductor when the interaction between the lattice vibrations and the electrons is sufficiently strong. The self-consistent method used by him is extended to finite temperatures, and the specific heat is calculated. It is shown that the model exhibits a second-order transition at a temperature which is related to the magnitude of the coupling constant. The approximations demand a coupling constant which is much larger than that of any real metal.

Publisher

The Royal Society

Subject

Pharmacology (medical)

Reference5 articles.

1. Elektronentheorie der M etallen.Berlin: Springer.

2. Proc. Roy;Frohlich H .;Soc. A,1954

3. Grobner W . & Hofreiter N . 1949 Integraltafel. Vienna: Springer.

4. W atson G. N . 1944 Theory of Bessel functions 2nd ed. Cambridge U niversity Press.

5. W hittaker E . T. & W atson G. N . 1927 M odem analysis 4th ed. Cambridge U niversity Press.

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