Abstract
The previous theory of Abragam & Pryce (1951) is extended to a special case of rhombic symmetry, and to include higher-order terms. The theory gives satisfactory agreement between the observed anisotropies of the
g
-tensor and the magnetic hyperfine structure, and shows that the size of the hyperfine structure is about 15 % smaller than would be expected on the assumption that the magnetic electron is confined to the copper ion. Comparison with the optical absorption spectrum suggests that the spin-orbit coupling is reduced by about the same amount, and the effects are explained by an overlap of the wave function of themagnetic electron on to neighbouring water molecules. The nuclear electric quadrupole moments are found to be (in units of 10
-24
cm
2
) ;
63
Cu, — 0.16;
65
Cu, — 0.15, with an estimated maximum error in the theory of 20 % .
Reference10 articles.
1. Theoretical Interpretation of Copper Fluosilicate Spectrum
2. Abragam A. & Pryce M. H. L. (referred to as AP) 1951 Proc. Roy. Soc. A 205 135; A 206 164.
3. Proc. Roy;Bleaney B.;Soc. A,1955
4. Proc. Roy;Bleaney B.;Soc. A,1955
5. Z. phys;Dreisch T.;Ghem. B,1937
Cited by
245 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献