Abstract
The orbitals of the ground state of a flat conjugated molecule are shown to be closely related to the orbitals of a certain excited state of the molecule. In this state, which is named the
standard
excited
state
, all the mobile electrons are in singly-occupied antisymmetrical or orbitals and have their spins parallel. These antisymmetrical orbitals can be transformed into equivalent orbitals which are each localized around one atom and so form a suitable basis for a method of calculating the ionization potentials of conjugated molecules. To illustrate the form of the equations obtained, the pyridine and aniline molecules are considered.
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