Abstract
An account is given of present ideas about the electron orbits in octahedral complexes containing 4
d
and 5
d
transition elements, with particular reference to paramagnetic resonance. The complex is treated by the method of molecular orbitals with the assumption that the magnetic carriers are partly in central
d
-orbits and partly in
p
π
-orbits round the outer nuclei. This is shown to lead to a reduction in the orbital
g
-factor and to the possibility of observing the hyperfine structure from the outer nuclei, thus testing the initial assumptions.
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