Abstract
Seven vibration-rotation bands of nitrous oxide have been measured with high resolution. The rotational fine structure of each has been analyzed and rotational constants have been derived. The value for
B
000
found from four bands is 0·4190
1
cm
-1
, agreeing very closely with that determined from the microwave spectrum. Values for the coefficients
α
i
for the different vibrational levels have been determined, and the occurrence of inconsistencies in the calculated values of
B
v
1
v
2
v
3
for higher vibrational levels confirms previous suggestions that resonance interactions may exist between different levels. Such interactions appear also to disturb the positions of the band origins.
Reference14 articles.
1. J;Bigeleisen J.;Chem. Phys.,1950
2. Spectrochim;Boyd D. R .;Acta,1952
3. Proc. Roy;Boyd D. R .;Soc. A,1953
4. Microwave Absorption Spectra ofN2O
5. Microwave Spectrum of CF3Cl
Cited by
16 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献