A method for the determination of collision-induced vibrational transition probabilities, with results for N 2 ( B 3 Π g )

A method for the determination of collision-induced vibrational transition probabilities, with results for N 2 ( B 3 Π g )—N 2 collisions

Published:1957-08-07 Issue:1225 Volume:241 Page:180-193
ISSN:0080-4630
Container-title:Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
language:en
Short-container-title:Proc. R. Soc. Lond. A

Author:

Abstract

Certain intensity changes arising in the spectrum of the nitrogen afterglow are attributed to collisional energy exchanges between the molecules. A method is described by which the probabilities of such exchanges can be derived from precise measurements of the intensity variations. For N 2 ( B 3 Π g )—N 2 collisions, the probability of a vibrational transition is found to be of the order of 10 -2 per gas-kinetic collision.

Publisher

The Royal Society

Subject

Pharmacology (medical)

Link

https://royalsocietypublishing.org/doi/pdf/10.1098/rspa.1957.0121

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1. Vibrational Relaxation and Electronic Quenching of the C 3Πu (υ′ = 1) State of Nitrogen;The Journal of Chemical Physics;1971-02

2. Studies of the Nitrogen Yellow Afterglow at Low Pressures;The Journal of Chemical Physics;1969-05

3. BIBLIOGRAPHY;Active Nitrogen;1968

4. Vibrational Deactivation of Excited States of Nitrogen created in a Microwave Discharge;Nature;1967-05

5. Relative transition probabilities for the B3 A3 system of nitrogen;Proceedings of the Physical Society;1966-03