Framework Fe-Doped Mobil Five (MFI) Zeolites as Highly Active and Stable Fenton-Like Catalysts for Basic Dyes Degradation

Author:

Deng Senlin1,Lv Guojun1,Zhai Yi1,Yang Zebin1,Zhu Yongqiang2,Li Haichao2,Wang Fumin1,Zhang Xubin1

Affiliation:

1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, P. R. China

2. College of Chemistry and Chemical Engineering, Qinghai Nationalities University, Xining 810007, P. R. China

Abstract

Highly active and stable framework Fe-doped ZSM-5 (f-Fe-ZSM-5) zeolites with different Fe contents, which were synthesized using a facile one-pot hydrothermal method, could effectively resolve the loss of iron element during the catalytic degradation of basic dyes. The successful introduction of Fe species into the framework of ZSM-5 was confirmed by elemental mappings, Fourier transform infrared (FT-IR) spectroscopy and Ultraviolet-visible spectroscopy (UV-vis spectra). The operational parameters, such as Fe content, H2O2 concentration, reaction temperature, types of dyes as well as the stability of the synthesized samples were extensively evaluated. It was demonstrated that the f-Fe(0.10)-ZSM-5 exhibited an efficient catalytic ability and excellent stability even after seven consecutive runs. The degradation efficiency of f-Fe-ZSM-5 for basic dyes was higher than that for acid dye. Therefore, f-Fe-ZSM-5 zeolites may present major potential for the treatment of basic dyes waste water without adjusting the initial pH value.

Publisher

American Scientific Publishers

Subject

Condensed Matter Physics,General Materials Science,Biomedical Engineering,General Chemistry,Bioengineering

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