Affiliation:
1. Department of Chemical Engineering, Kyung Hee University, Gyeonggi, 17104, Republic of Korea
2. Research Center for Green Fine Chemicals, Korea Research Institute of Chemical Technology, Ulsan, 44412, Republic of Korea
Abstract
New triazene based metal complexes such as Cu[1-(phenyldiazenyl)piperidine]2Br2 (BTACHCuBr2), Cu[1-(phenyldiazenyl)piperidine]2Cl2 (BTACH-CuCl2), Ni[1-(phenyldiazenyl)piperidine]2Cl2 (BTACH-NiCl2 · 6H2O),
Cu[2,2,6,6-tetramethyl-1-(phenyldiazenyl)piperidine]2Cl2 (BTACM-SnCl2), Ti[2,2,6,6-tetramethyl-1-(phenyldiazenyl)piperidine]2Cl2 (BTACM-TiCl2) were synthesized. All of the five compounds did not absorb in the visible light wavelength region and it
does not have the color change disadvantage when using as an additive in polymerization. All materials also had thermal stability up to 245 °C. Among the synthesized compounds, BTACH-CuBr2 showed the best radical inhibitor property when n-hexyl acrylate monomer was polymerized
with the synthesized metal complexes at 150 °C isothermal condition. It exhibited more than 5 times of the polymerization delayed initiation compared to other synthesized metal complexes cases.
Publisher
American Scientific Publishers
Subject
Condensed Matter Physics,General Materials Science,Biomedical Engineering,General Chemistry,Bioengineering
Cited by
1 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献