Synthesis and Electrochemical Properties of MoS2/rGO/S Composite as a Cathode Material for Lithium–Sulfur Batteries

Author:

Reddy Bhumi Reddy Srinivasulu1,Premasudha Mookala1,Lee Yeon-Ju1,Ahn Hyo-Jun1,Reddy Nagireddy Gari Subba2,Ahn Jou-Hyeon3,Cho Kwon-Koo1

Affiliation:

1. Department of Materials Engineering and Convergence Technology & Research Institute for Green Energy Convergence Technology Gyeongsang National University 501, Jinju-daero, Jinju-si, Gyeongsangnam-do 52828, Republic of Korea

2. School of Materials Science and Engineering, Gyeongsang National University, 501 Jinju-daero, Jinju-si, Gyeongsangnam-do 52828, Republic of Korea

3. Department of Chemical Engineering & RIGET, Gyeongsang National University, 501, Jinju-daero, Jinju-si, Gyeongsangnam-do 52828, Republic of Korea

Abstract

To develop the next-generation energy storage systems, lithium-sulfur batteries represent an attractive option due to its high theoretical capacity, and energy density. In this work, MoS2/rGO (reduced graphene oxide) was prepared by hydrothermal synthesis and sulfur added by the melt diffusion method. The as-prepared MoS2/rGO has strong polysulfides entrapping, high conductivity, large surface area, and high catalytic activity, consequently resulting in enhanced rate performance and cycling capability of Li-S batteries. The coin cells were constructed with the MoS2/rGO/S cathode material, exhibit a high reversible capacity of nearly 1380 mAh/g at 0.1 C, outstanding cycling stability with a low capacity fading rate. Present work reveals that the hierarchal MoS2/rGO/S cathodes are potential candidate materials for future high-performance lithium-sulfur batteries.

Publisher

American Scientific Publishers

Subject

Condensed Matter Physics,General Materials Science,Biomedical Engineering,General Chemistry,Bioengineering

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