Sinterability and Luminescence Property of the MgO-YAG:Ce Phosphor Ceramic with Sintering Aids

Author:

Yu Huaqian1,Zhao Huanyu1,Zhang Mu1,Peng Haijun2,Sun Xudong1

Affiliation:

1. School of Materials Science and Engineering, Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), Northeastern University, Shenyang 110819, Liaoning, PR China

2. Science and Technology on Advanced Ceramic Fibers and Composites Laboratory, National University of Defense Technology, Changsha 410073, China

Abstract

MgO-YAG:Ce phosphor ceramics with the addition of Y2O3, SiO2, TiO2 and ZrO2 as sintering aids were developed from commercial powders by hot-pressing. In this work, the effects of Y2O3, SiO2, TiO2, ZrO2 on the phase composition, microstructure, sinterability and luminescence intensity of MgO-YAG:Ce phosphor ceramic were investigated. By comparison, the relative density of MgO-YAG:Ce phosphor ceramic with 2 wt.% SiO2 was satisfying, reaching 98.4%, and the luminescence intensity reached the maximum. Because SiO2 and MgO react to form interstitial solid solution Mg2SiO4, which leads to the increase of the grain boundary energy of the MgO matrix, thereby increasing the sintering performance of MgO-YAG:Ce phosphor ceramics. And SiO2 does not react with YAG, maintaining the excellent luminescence properties of YAG itself.

Publisher

American Scientific Publishers

Subject

Electrical and Electronic Engineering,Electronic, Optical and Magnetic Materials

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