Effect of TiCl4 Post-Treatment on the Embedded-Type TiO2 Nanotubes Dye-Sensitized Solar Cells
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Published:2015-10-01
Issue:10
Volume:15
Page:7845-7847
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ISSN:1533-4880
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Container-title:Journal of Nanoscience and Nanotechnology
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language:en
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Short-container-title:j nanosci nanotechnol
Author:
Kim Kang-Pil,Kim Jeong-Hwa,Hwang Dae-Kue,Sung Shi-Joon,Heo Young-Woo
Abstract
We have studied the effect of TiCl4 post-treatment on the embedded-type TiO2 nanotubes (NT)-dyesensitized solar cells (DSSCs). The TiO2 nanoparticles layer formed on TiO2 NTs surface by TiCl4 post-treatment showed different morphologies
depending on TiCl4 treatment temperature. These different morphologies influenced the cell efficiency of TiO2 NT-DSSCs. The TiO2 NT treated with TiCl4 at 50 °C exhibited a rougher surface than that treated at 70 °C. The rough surface of the
TiO2 NT improved the charge exchange between the dye and electrolyte. The TiO2 NT treated with TiCl4 at 50 °C showed better fill factor and cell efficiency than that treated at 70 °C. The TiCl4 post-treatment of TiO2 NT was effective
at conditions of low temperature and long times. The TiO2 NT-DSSCs with TiCl4 post-treatment at 50 °C for 1.5 h showed an efficiency of 6.52%.
Publisher
American Scientific Publishers
Subject
Condensed Matter Physics,General Materials Science,Biomedical Engineering,General Chemistry,Bioengineering
Cited by
1 articles.
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1. Function of
TiCl
4
Posttreatment in Photoanode;Interfacial Engineering in Functional Materials for Dye‐Sensitized Solar Cells;2019-11-08