Synthesis and Crystal Structure of a Novel Organo-Inorganic Hybrid Borate, K[B5O6(OH)4][B(OH)3]2(H2O)(C10H20O5)2-Reference-Cited by-同舟云学术

Synthesis and Crystal Structure of a Novel Organo-Inorganic Hybrid Borate, K[B5O6(OH)4][B(OH)3]2(H2O)(C10H20O5)2

Published:2023-09-01 Issue:5 Volume:49 Page:532-537
ISSN:0132-6651
Container-title:Физика и химия стекла
language:
Short-container-title:Fizika i himiâ stekla

Author:

Yukhno V. A.¹,Charkin D. O.²³,Volkov S. N.¹³,Manelis L. S.²³,Gosteva A. N.⁴,Aksenov S. M.³,Bubnova R S.¹

Affiliation:

1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

2. Department of Chemistry, Moscow State University, 119991, Moscow, Russia

3. Laboratory of Arctic Mineralogy and Materials Sciences, Federal Research Center “Cola Science Center,” Russian Academy of Sciences, 184209, Apatity, Murmansk oblast, Russia

4. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Federal Research Center “Cola Science Center,” Russian Academy of Sciences, 184209, Apatity, Murmansk oblast, Russia

Abstract

Crystals of a novel hybrid organo-inorganic borate, K[B5O6(OH)4][B(OH)3]2(H2O)(C10H20O5)2 (1), were obtained from aqueous solutions and characterized by single-crystal X-ray diffraction and IR spectroscopy. 1 is triclinic (a = 10.1567(4), b = 11.9941(6), c = 17.1893(9) Å, α = 75.280(4), β = 79.406(4), γ = 88.531(4)°, V = 1990.270369 Å3, SG P-1; R1 = 0.058). Its structure contains [K(C10H20O5)2]+ groups which behave as “hydrophobic” templates for the inorganic part comprised of B5O6(OH)4 anions and neutral B(OH)3 molecules.

Publisher

The Russian Academy of Sciences

Reference19 articles.

1. Becker P. Borate materials in nonlinear optics //Advanced Materials. 1998. V. 10. № 13. P. 979–992.

2. Chen C., Sasaki T., Li R., Wu Y., Lin Z., Mori Y., Kaneda Y. Nonlinear optical borate crystals: Principals and applications // John Wiley & Sons, 2012.

3. Mutailipu M., Pan S. Emergent deep-ultraviolet nonlinear optical candidates // Angewandte Chemie International Edition. 2020. V. 59. № 46. P. 20302–20317.

4. Mutailipu M., Poeppelmeier K.R., Pan S. Borates: a rich source for optical materials // Chemical Reviews. 2020. V. 121. № 3. P. 1130–1202.

5. Sasaki T., Mori Y., Yoshimura M., Yap Y.K., Kamimura T. Recent development of nonlinear optical borate crystals: key materials for generation of visible and UV light // Materials Science and Engineering: R: Reports. 2000. V. 30. № 1–2. P. 1–54.