Synthesis of C₆₀ fullerene hybrid molecules with catecholamines under the action of ultrasound

Abstract

For the first time, morpholine monoadducts of С60-fullerene were obtained in the reactions of fullerene with biogenic amines (norepinephrine, adrenaline) under the action of ultrasound. The reactions take place in air in ( g 2.0000 and Δ H 1/2 3.2 G) was detected by EPR, a key intermediate in the synthesis of the C60-adrenaline cycloadduct, which was obtained as a result •-a toluene/DMF medium at room temperature. The radical anion C60- of a one-electron transition from the adrenaline molecule to the C60 framework.