Affiliation:
1. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences
Abstract
The synthetic potential of adducts of acetylenic and allenic carbanions with isothiocyanates and azatrienic systems based on them - precursors of fundamental aza- and thiaheterocycles - pyrroles, 2,3-dihydropyridines, pyridines, quinolines, 3 H -azepines, 4,5-dihydro-3 H -azepines, 2-azabicyclo[3.2.0]hept-2-енов, thietanes, thiophenes, thiophene-2(5 H )-imines, 1,3-thiazoles, 4,5-dihydro-1,3-thiazoles, and other heterocyclic structures with rare and/or difficult-to-build functional and pharmacophore substituents is briefly described.
Publisher
The Russian Academy of Sciences
Reference161 articles.
1. Preparation, metallation and alkylation of allenyl ethers
2. Brandsma L., Verkruijsse H.D. Studies in Organic Chemistry. 8. Synthesis of Acetylenes, Allenes and Cumulenes: A Laboratory Manual. Amsterdam: Elsevier, 1981.
3. Epsztein R. The Formation and Transformations of Allenic-Acetylenic Carbanions. In Studies in Organic Chemistry. 5. Comprehensive Carbanion Chemistry. Part B. Selectivity Carbon-Carbon Bond Forming Reactions. Eds. E. Buncel, T. Durst. Amsterdam: Elsevier, 1984.
4. Brandsma L., Verkruijsse H. Preparative Polar Organometallic Chemistry. Berlin: Springer-Verlag, 1987, 1.
5. Brandsma L. Studies in Organic Chemistry. 34. Preparative Acetylenic Chemistry. Amsterdam: Elsevier, 1988.