Synthesis and Structure of Trisubstituted closo-Decaborane [B10H7(1-IPh)(6(7),10-NHOCCH3)]: Specifics of Interaction between the [2-B10H9NH=C(OH)CH3]– Ion and PhI(OAc)2-Reference-Cited by-同舟云学术

Synthesis and Structure of Trisubstituted closo-Decaborane [B10H7(1-IPh)(6(7),10-NHOCCH3)]: Specifics of Interaction between the [2-B10H9NH=C(OH)CH3]– Ion and PhI(OAc)2

Published:2023-06-01 Issue:6 Volume:68 Page:761-767
ISSN:0044-457X
Container-title:Журнал неорганической химии
language:
Short-container-title:Žurnal neorganičeskoj himii

Author:

Voinova V. V.¹,Selivanov N. A.¹,Bykov A. Yu.¹,Kubasov A. S.¹,Zhdanov A. P.¹,Zhizhin K. Yu.¹,Kuznetsov N. T.¹

Affiliation:

1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Abstract

The preparation of trisubstituted closo-decaboranes by reacting 1,2-boroxazoles with PhI(OAc)2 was studied. The process could be implemented in a one-pot variant proceeding from borylated iminol. The reaction products were characterized by 1H, 11B, and 13C NMR spectroscopy. The XRD structure of the compound [B10H7(1-IPh)(6,10-NHOCCH3)] was determined.

Publisher

The Russian Academy of Sciences

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