Solid solutions of pyridinium halobismuthates-Reference-Cited by-同舟云学术

Solid solutions of pyridinium halobismuthates

Published:2024-07-28 Issue:2 Volume:69 Page:177-182
ISSN:0044-457X
Container-title:Журнал неорганической химии
language:
Short-container-title:Žurnal neorganičeskoj himii

Author:

Buikin P. A.¹²,Zhavoronkov A. S.²,Ilyukhin A. B.²,Kotov V. Yu.¹²

Affiliation:

1. HSE University

2. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Abstract

Solid solutions of pyridinium bromo-iodobismutates were isolated from aqueous solutions and structurally characterized. The composition of the resulting solid solutions [HPy]BiX4 and [HPy]3Bi2X9 (X = Br, I) was found to depend on the ratios of pyridinium/bismuth and bromine/iodine in the initial solution. The existence of five polymorphic modifications in the system for [HPy]BiX4 compounds was shown. Two different polymorphs were found for iodobismuthate [HPy]BiI4.

Publisher

The Russian Academy of Sciences

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