Study of the Photoreaction of Methyladamantylthione Using Chemical Nuclear Polarization-Reference-Cited by-同舟云学术

Study of the Photoreaction of Methyladamantylthione Using Chemical Nuclear Polarization

Published:2023-03-01 Issue:3 Volume:97 Page:434-437
ISSN:0044-4537
Container-title:Журнал физической химии
language:
Short-container-title:Russian Journal of Physical Chemistry

Author:

Porkhun V. I.¹,Kuznetsova N. A.¹,Savelyev E. N.¹

Affiliation:

1. Volgograd State Technical University

Abstract

The article presents the results of our study of the mechanisms of the photoreactions of methyladamantylthione AdCSCH3 (I) using chemical nuclear polarization (CNP) effects, which show themselves in the NMR spectra. While pulsed and laser photolysis allows us to study the kinetics of death and accumulation of intermediates released from the solvent cell, the use of CNP allows us to study cell processes in detail. The elementary acts of the reaction were established and proved experimentally.

Publisher

The Russian Academy of Sciences

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