Synthesis and Functionalization of Unsymmetrical Terbium(III) Bis-Phthalocyaninates, Promising Components of Hybrid Magnetic Materials-Reference-Cited by-同舟云学术

Synthesis and Functionalization of Unsymmetrical Terbium(III) Bis-Phthalocyaninates, Promising Components of Hybrid Magnetic Materials

Published:2023-09-01 Issue:9 Volume:68 Page:1146-1153
ISSN:0044-457X
Container-title:Журнал неорганической химии
language:
Short-container-title:Žurnal neorganičeskoj himii

Author:

Yagodin A. V.¹,Kormshchikov I. D.²,Martynov A. G.¹,Gorbunova Yu. G.¹³,Tsivadze A. Yu.¹³

Affiliation:

1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

2. Faculty of Chemistry, Moscow State University

3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Abstract

A new unsymmetrical terbium bis-Phthalocyaninate Tb(A7B) with one terminal aliphatic OH group was obtained by template cross-condensation of diethoxyphthalonitrile (A) and phthalonitrile (B) functionalized with diethylene glycol moiety. The subsequent functionalization of the complex included the successive replacement of this OH group by the iodide and thioacetate substituents. The synthesized complexes can act as components of hybrid materials upon immobilization on surfaces of various nature.

Publisher

The Russian Academy of Sciences

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