Correction of the 3D Computer Model of the Phase Diagram for the LiCl–PrCl3–KCl System Using Thermoanalytical Curves-Reference-Cited by-同舟云学术

Correction of the 3D Computer Model of the Phase Diagram for the LiCl–PrCl3–KCl System Using Thermoanalytical Curves

Published:2023-08-01 Issue:8 Volume:68 Page:1090-1098
ISSN:0044-457X
Container-title:Журнал неорганической химии
language:
Short-container-title:Žurnal neorganičeskoj himii

Author:

Vorob’eva V. P.¹,Zelenaya A. E.¹,Lutsyk V. I.¹,Parfenova M. D.¹,Baldanov V. D.¹

Affiliation:

1. Institute of Physical Materials Science, Siberian Branch of the Russian Academy of Sciences

Abstract

A spatial (3D) computer model of an isobaric phase diagram of the LiCl–PrCl3–KCl system was designed. The model was assembled of 66 surfaces and 27 phase regions, of which 31 surfaces and 14 phase regions degenerate to verticals or vertical planes because of the limited solubilities of the initial chlorides and their compounds. Published experimental isothermal sections and thermoanalytical curves for 33 salt melts were used to improve the quality of the 3D model. The results can be used to improve the molten-salt refining technology of nuclear fuel waste.

Publisher

The Russian Academy of Sciences

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