Complexes of Zinc Nitrate and Lanthanide Nitrates with Urea in the 1 : 2 Ratio

Author:

Karavaev I. A.1,Savinkina E. V.1,Ponkrashina S. S.1,Grigor’ev M. S.2

Affiliation:

1. Lomonosov Institute of Fine Chemical Technologies, MIREA—Russian Technological University

2. Frumkin Institute of Physical Chemistry and Electrochemistry

Abstract

Coordination compounds [Zn(H2O)4(Ur)2](NO3)2, [M(H2O)2(Ur)2(NO3)3] (M = Ce, Nd), and [Dy(H2O)(Ur)2(NO3)3] have been synthesized by the reaction of nitrates of zinc or rare earth elements with urea (Ur) in an aqueous solution. Their composition has been determined and structural features have been established using elemental analysis, IR spectroscopy, and X-ray diffraction analysis. For the zinc complex, a polymorphic transition has been found at 181 K.

Publisher

The Russian Academy of Sciences

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3. Николаева Н.С., Иванов В.В., Шубин А.А. // Журн. Сибирского федерального университета. Химия. 2010. Т. 3. № 2. С. 153

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