Growth Conditions and the Structural and Magnetic Properties of Cu2MBO5 (M = Cr, Fe, Mn) Oxyborates with a Ludwigite Structure-Reference-Cited by-同舟云学术

Growth Conditions and the Structural and Magnetic Properties of Cu2MBO5 (M = Cr, Fe, Mn) Oxyborates with a Ludwigite Structure

Published:2023-12-15 Issue:1 Volume:163 Page:24-34
ISSN:0044-4510
Container-title:Журнал экспериментальной и теоретической физики
language:
Short-container-title:Žurnal èksperimentalʹnoj i teoretičeskoj fiziki

Author:

Moshkina E. M¹,Bel'skaya N. A²,Molokeev M. S¹³,Bovina A. F¹,Shabanova K. A⁴,Kokh D.⁵⁴,Seretkin Yu. V⁶⁷,Velikanov D. A¹,Eremin E. V¹,Krylov A. S.¹,Bezmaternykh L. N¹

Affiliation:

1. Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences

2. Ioffe Institute, Russian Academy of Sciences

3. Far-Eastern State Transport University

4. Russia Federal Research Center, Siberian Branch, Russian Academy of Sciences

5. Siberian Federal University

6. Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences

7. Novosibirsk State University

Abstract

Copper oxyborate single crystals with a ludwigite structure, Cu2MBO5 (M = Cr, Fe, Mn), containing different substitutes in the trivalent subsystem have been grown from Bi2O3–MoO3–Na2O–B2O3 fluxes. The structural properties of grown compounds have been compared in detail using X-ray diffraction and Raman spectroscopy methods. In addition, these methods have been used to determine the degree of cationic ordering in these ludwigites. The temperature and field dependences of the Cu2MBO5 (M = Cr, Fe, Mn) ludwigite magnetization are presented.

Publisher

The Russian Academy of Sciences

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