Radiolytic modification of polymer filler for cement compositions

Author:

Kholodkova E. M.1,Nevolin Yu. M.1,Shapagin A. V.2,Grafov O. Yu.1,Ponomarev A. V.1

Affiliation:

1. A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

2. A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences Leninsky prospekt 31(4), Moscow, 119071 Russia

Abstract

The influence of preliminary irradiation (3 MeV electron beam) of powdered (≤0.2 mm) synthetic polymers (polyethylene, polypropylene, polyvinyl chloride, polycarbonate, polyethylene terephthalate, or polystyrene) on the compressive strength of cement-sand-polymer compositions has been studied. The surface oxidation of the powders was ensured by irradiation in air or in a water-air mixture. It is shown that the oxidation of the powder in an aqueous medium, as well as the post-radiation alkalization of the powders, contribute to a higher strength of the composites. Oxidation of the powder in air leads to a relative decrease in the strength of the composite due to a higher yield of acid formation.

Publisher

The Russian Academy of Sciences

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