Synthesis of 5-[4-(arylsulfanyl)phenyl]-2,2′-bipyridines using aryne intermediates

Author:

Starnovskaya E. S12,Krinochkin A. P12,Rybakova S. S1,Muzyka A. L1,Slepukhin P. A12,Kopchuk D. S12,Zyryanov G. V12,Chupakhin O. N12

Affiliation:

1. Ural Federal University

2. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences

Abstract

A convenient method for the preparation of 5-aryl-2,2′-bipyridines with para -arylsulfanyl group in an aromatic substituent was proposed. The synthesis was performed using in situ generated aryne intermediates without the use of complex experimental procedures and expensive reagents/catalysts. The structure of one product was confirmed by XRD data. This approach is a new variant for the preparation of 5-aryl-2,2’-bipyridines with an extended conjugation system.

Publisher

The Russian Academy of Sciences

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