Colloidal and nanosized catalysts in organic synthesis: XXV. Reductive alkylation of nitroarenes with alcohols in the presence of a supported copper nanocatalyst-Reference-Cited by-同舟云学术

Colloidal and nanosized catalysts in organic synthesis: XXV. Reductive alkylation of nitroarenes with alcohols in the presence of a supported copper nanocatalyst

Published:2023-03-15 Issue:3 Volume:93 Page:331-337
ISSN:0044-460X
Container-title:Журнал общей химии
language:
Short-container-title:Žurnal obŝej himii

Author:

Nebykov D. N¹,Razvalyaeva A. V¹,Panov A. O¹,Latyshova S. E¹,Mokhov V. M¹

Affiliation:

1. Volgograd State Technical University

Abstract

Using a modified deposition-precipitation method followed by sodium borohydride reduction of the precursor deposited on γ-Al2O3, copper-containing catalysts were obtained, which allow the continuous process of reductive alkylation of nitroarenes with alkanols at 200-220°C and atmospheric pressure of hydrogen with mono- N -alkylated products selectivity up to 100% and complete conversion of nitroarenes.

Publisher

The Russian Academy of Sciences

Reference24 articles.

1. Попов Ю.В., Мохов В.М., Небыков Д.Н., Ширханян П.М., Гендлер Т.А., Шемет В.В. // ЖОХ. 2020. Т. 90. Вып. 6. С. 823

2. КОЛЛОИДНЫЕ И НАНОРАЗМЕРНЫЕ КАТАЛИЗАТОРЫ В ОРГАНИЧЕСКОМ СИНТЕЗЕ: XXIV. ИЗУЧЕНИЕ ПРОЦЕССА ГИДРИРОВАНИЯ ФУРАНА И ЕГО ПРОИЗВОДНЫХ В ПРИСУТСТВИИ НАНЕСЕННЫХ НА MGO НАНОЧАСТИЦ НИКЕЛЯ И КОБАЛЬТА

3. One-pot synthesis of aniline derivatives from nitroarenes under mild conditions promoted by a recyclable polymer-supported palladium catalyst

4. One-pot reductive amination of aldehydes with nitroarenes over an Au/Al2O3 catalyst in a continuous flow reactor

5. Conducting Poly(N -propylaniline) Nanoparticles for Hydrogen Sulfide Gas Detection