Affiliation:
1. Khlopin Radium Institute
2. St. Petersburg State University
3. Ozersk Technological Institute of the National Research Nuclear University
4. St. Petersburg State Pediatric Medical University
Abstract
«2+1» tricarbonyl complexes [M(CO)3(N^N)CN(CH2)10COOMe]ClO4, where M = Tc or Re and N^N = 2,2′-bipridine (bipy) or 1,10-phernanthroline (phen), were prepared by reaction of [M(CO)3(N^N)(MeOH)]ClO4 with methyl 11-isocyanoundecanoate in methanol. The complexes were isolated and characterized by IR, 1H NMR spectroscopy and elemental analysis. Stability of the «2+1» tricarbolyl complexes with respect to transchelation with histidine was studied.
Publisher
The Russian Academy of Sciences