Affiliation:
1. I.Ya. Postovskii Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
2. Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences
Abstract
The photolytic decomposition of the Trikhlorbifenil mixture, 2,4,5- and 2,4,6-trichlorobiphenyls under an influence of ultraviolet radiation in presence of tungsten oxide as a catalyst in a methanol medium was studied. A higher rate of photolysis of individual congeners of polychlorbiphenyls was established compared to the congeners of the Trikhlorbifenil mixture. The influence of structural features of polychlorarenes on a depth of photodecomposition and a routes of formation of photodestruction products was considered.
Publisher
The Russian Academy of Sciences