Nucleophilic substitution in 4-bromo-5-nitrophthalodinitrile: XVIII. Synthesis and spectral properties of octasubstituted zinc phthhalocyanines with cyclohexylphenol moieties

Author:

Znoiko S. A1,Kuzmina M. S1,Maizlish V. E1,Koshel G. N2,Lebedeva N. V2

Affiliation:

1. Research Institute for the Chemistry of Macroheterocycles, Ivanovo State University of Chemistry and Technology

2. Yaroslavl State Technical University

Abstract

Using 4-bromo-5-nitro- and 4,5-dichlorophthalonitriles, substituted phthalonitriles containing a fragment of 2-cyclohexylphenol and nitro- or 1-benzotriazolyl groups, as well as phthalonitrile containing two 2-cyclohexylphenoxy groups, were synthesized. Tetramerization of these precursors with zinc acetate hexahydrate gave the corresponding octa-substituted zinc phthalocyanines. Their spectral properties were studied.

Publisher

The Russian Academy of Sciences

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