New reactions of acetylene generated in two-chamber reactor

Abstract

For the first time reactions of acetylene generated in a two-chamber reactor with methyl diazoacetate, iodine and benzoyl chlorides were studied. Methyl 1 H -pyrazole-3-carboxylate, ( E )-1,2-diiodoethylene, ( E )-1,2-dideutero-1,2-diiodoethylene, (2 E )-1-aryl-3-chloroprop-2-en-1-ones, including D-labeled 3-chloro-2,3-dideutero1-phenylprop-2-en-1-one were synthesized.