Synthesis of polyfunctional O-containing 1,3-dioxepines connected with an acetal fragment by low-temperature ozonolysis-Reference-Cited by-同舟云学术

Synthesis of polyfunctional O-containing 1,3-dioxepines connected with an acetal fragment by low-temperature ozonolysis

Published:2024-07-19 Issue:1 Volume:514 Page:27-31
ISSN:2686-9535
Container-title:Доклады Российской академии наук. Химия, науки о материалах
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Short-container-title:Doklady Rossijskoj akademii nauk. Himiâ, nauki o materialah.

Author:

Belyaeva E. R.¹,Borisova Yu. G.¹,Raskildina G. Z.¹,Sultanova R. M.¹,Zlotsky S. S.¹

Affiliation:

1. Ufa State Petroleum Technological University (USPTU)

Abstract

The synthesis of 3,5-dioxo-1,7-heptandials, 3,5-dioxo-1,7-heptanediols and 1,3-dioxo-1,7-heptanedicarboxylic acid derivatives by low-temperature ozonolysis of 1,3-dioxepines was carried out for the first time. It is shown that, depending on the conditions of destruction of the intermediate peroxide products of ozonolysis, the corresponding individual dialdehydes, diols, and diesters can be synthesized with high selectivity.

Publisher

The Russian Academy of Sciences

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